FCC Exam Question: 6A264

Decrease in capacity of an Edison-type storage cell can be caused by:

A. Frequent overheating, and operating conditions over 115 degrees fahrenheit
B. Charging at less than the normal rate
C. Adding impure water to the electrolyte, or a weak or aged electrolyte
D. All of the above
Correct Answer: D

Explanation: Edison-type (nickel-iron) storage cells are robust but susceptible to various factors that reduce their capacity. Frequent overheating (A) accelerates internal degradation of the electrodes and separators, increases self-discharge rates, and can lead to irreversible chemical changes, all diminishing the cell's ability to store charge. Charging at less than the normal rate (B), if it results in consistent undercharging, means the battery is never brought to its full potential, effectively reducing its usable capacity over time. Inefficiently slow charging might also not fully overcome internal resistance. Adding impure water or using a weak or aged electrolyte (C) significantly impairs performance. Impurities can introduce unwanted chemical reactions, contaminate the electrodes, or increase internal resistance. A degraded or weak potassium hydroxide electrolyte cannot efficiently participate in the charge-discharge cycles, directly lowering the cell's capacity. Therefore, all these conditions compromise the chemical integrity and operational efficiency of an Edison cell, leading to a decrease in its energy storage capacity.

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Includes Elements 1, 3, 6, 7R, 8, and 9.